Contributions to the knowledge
of the Van der Waals ψ-surface II
The part of the transverse plait in the neighborhood of the plaitpoint
in Kuenens experiments on retrograde condensation
Abstract by Johanna Levelt Sengers
This short note describes an amazing experment that Kamerlingh
Onnes performed after he had obtained a few liters of helium gas
for the first time, only 1½ years prior to the liquefaction
of helium. Kamerlingh Onnes pressed helium gas into a glass container
filled with liquefied hydrogen at its boiling point of 20 K, far
below the hydrogen critical point of 33 K, but far above that
of helium, then unknown. As he increased the pressure, the density
of the helium-rich vapor exceeded that of the hydrogen-rich liquid,
after which the vapor and liquid exchanged their positions in
the tube. The experiment fascinated Van der Waals, who explained
this barotropic phenomenon at the Academy a month later. Up to
the highest pressures he could reach in the glass tube, Kamerlingh
Onnes could not make the two phaeses mix, fore-shadowing the phenomenon
of gas-gas phase separation.
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